Enhancing Stoichiometric Methane-Air Flames: The Role of N2O Replacement
Abstract
The oxidizer is used in aviation propellants for its relatively high impulse density and non-toxic nature. At elevated temperatures, nitrous oxide (Nâ‚‚O) decomposes into approximately 33% oxygen (Oâ‚‚) and 67% nitrogen (Nâ‚‚), providing a higher oxygen content than ambient air. This decomposition enables Nâ‚‚O to produce higher flame temperatures than air. Previous studies have shown that Nâ‚‚O addition improves flame stability in methane combustion systems. This study examined the substitution of Oâ‚‚ with Nâ‚‚O in stoichiometric methane”“air premixed flames, using both numerical and experimental methods. One-dimensional and two-dimensional simulations with CHEMKIN PRO revealed that replacing air with Nâ‚‚O increases flame temperature but reduces laminar flame speed, mainly due to lower local oxygen concentrations in the reaction zone. The simulations also showed that nitrogen oxides (NOâ‚“) emissions increase significantly in the post-reaction zone, while carbon monoxide (CO) and carbon dioxide (COâ‚‚) emissions decrease. Experimental results confirmed that controlled Nâ‚‚O addition enhances flame stability, but excessive concentrations can trigger combustion instabilities. Overall, the findings indicate that introducing up to 20% Nâ‚‚O can increase flame temperature and reduce CO emissions in methane flames.
Keywords
Nitrous Oxide; Methane-air flame; Flame stability; NOx emission; Flame speedReferences
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