Automotive Experiences

Articles

Probabilistic Performance Prediction of a Hydrogen-Converted SI Engine Using a Markov-Chain-Wiebe Framework

Purnami , Willy Satrio Nugroho , Lilis Yuliati , Fikrul Akbar Alamsyah , Abdul Mudjib Sulaiman Wahid , I Nyoman Gede Wardana

Abstract

This study employs a novel Markov-chain modeling framework to analyze the combustion-performance interaction in a hydrogen-fueled spark-ignition engine. The methodology integrates a Wiebe heat-release model within a Markov-chain state-transition framework, where each discrete engine state defines combustion parameters and probabilistic transitions capture cycle-to-cycle variability. Results demonstrate that engine behavior is dominantly governed by combustion phasing, with spark timing exerting primary control over torque, efficiency, and brake-specific fuel consumption (BSFC). Sensitivity analysis confirms spark timing produces the steepest performance gradients, while ignition voltage offers secondary benefits and engine speed exhibits minimal influence. The model reveals a highly nonlinear torque response to spark advance, characterized by a rapid rise culminating in a narrow maximum brake torque (MBT) plateau at 8°–10° BTDC, corresponding to a distinct BSFC minimum. Significant data scatter underscores the stochastic nature of hydrogen combustion, arising from multidomain interactions between air-fuel ratio, ignition strength, and phasing. The Markov-chain approach successfully captures this coupled deterministic-probabilistic behavior, highlighting the critical need for precise spark-timing control to optimize performance in hydrogen applications.

Keywords

Hydrogen internal combustion engine; Combustion phasing; Spark ignition; Markov-chain; Performance Prediction

References

  1. [1] K. Wróbel, J. Wróbel, W. Tokarz, J. Lach, K. Podsadni, and A. Czerwiński, “Hydrogen Internal Combustion Engine Vehicles: A Review,” Energies, vol. 15, no. 23, p. 8937, Nov. 2022, doi: 10.3390/en15238937.
  2. [2] P. Purnami, W. Satrio Nugroho, Y. K. Sofi’i, and I. N. G. Wardana, “The impact of sodium lauryl sulfate on hydrogen evolution reaction in water electrolysis,” International Journal of Hydrogen Energy, vol. 79, pp. 1395–1405, Aug. 2024, doi: 10.1016/j.ijhydene.2024.07.127.
  3. [3] Z. Hammi, N. Labjar, M. Dalimi, Y. El Hamdouni, E. M. Lotfi, and S. El Hajjaji, “Green hydrogen: A holistic review covering life cycle assessment, environmental impacts, and color analysis,” International Journal of Hydrogen Energy, vol. 80, pp. 1030–1045, Aug. 2024, doi: 10.1016/j.ijhydene.2024.07.008.
  4. [4] P. Purnami, N. Willy Satrio, S. Supriyono, and I. N. G. Wardana, “Digitally controlled organic electrocatalyst for water electrolysis,” International Journal of Hydrogen Energy, vol. 47, no. 23, pp. 11877–11893, Mar. 2022, doi: 10.1016/j.ijhydene.2022.01.203.
  5. [5] T. Li, X.-G. Yue, M. Qin, and D. Norena-Chavez, “Towards Paris Climate Agreement goals: The essential role of green finance and green technology,” Energy Economics, vol. 129, p. 107273, Jan. 2024, doi: 10.1016/j.eneco.2023.107273.
  6. [6] Z. Yang, J. Wu, H. Yun, H. Zhang, and J. Xu, “Diagnosis and control of abnormal combustion of hydrogen internal combustion engine based on the hydrogen injection parameters,” International Journal of Hydrogen Energy, vol. 47, no. 35, pp. 15887–15895, Apr. 2022, doi: 10.1016/j.ijhydene.2022.03.031.
  7. [7] P. P. Brancaleoni, E. Corti, V. Ravaglioli, D. Moro, and G. Silvagni, “Innovative torque-based control strategy for hydrogen internal combustion engine,” International Journal of Hydrogen Energy, vol. 73, pp. 203–220, Jul. 2024, doi: 10.1016/j.ijhydene.2024.05.481.
  8. [8] Y. Zhou, Q. Ruan, Y. Li, Y. Fan, and D. Chen, “A full in-silico approach for quantifying the effect of intramolecular hydrogen bonds on physicochemical properties,” Journal of Molecular Liquids, vol. 425, p. 127152, May 2025, doi: 10.1016/j.molliq.2025.127152.
  9. [9] D. N. Rrustemi, L. C. Ganippa, T. Megaritis, and C. J. Axon, “New laminar flame speed correlation for lean mixtures of hydrogen combustion with water addition under high pressure conditions,” International Journal of Hydrogen Energy, vol. 63, pp. 609–617, Apr. 2024, doi: 10.1016/j.ijhydene.2024.03.177.
  10. [10] D. Saini, M. Talei, Y. Yang, R. D. Sandberg, and J. D. Berry, “Improving low-order modelling of cryogenic hydrogen releases,” International Journal of Hydrogen Energy, vol. 105, pp. 417–426, Mar. 2025, doi: 10.1016/j.ijhydene.2025.01.148.
  11. [11] V. Y. Plaksin and I. A. Kirillov, “Hydrogen flammability and explosion concentration limits for a wide temperature range,” Journal of Loss Prevention in the Process Industries, vol. 94, p. 105554, Apr. 2025, doi: 10.1016/j.jlp.2025.105554.
  12. [12] H. Sapra, M. Godjevac, P. De Vos, W. Van Sluijs, Y. Linden, and K. Visser, “Hydrogen-natural gas combustion in a marine lean-burn SI engine: A comparitive analysis of Seiliger and double Wiebe function-based zero–dimensional modelling,” Energy Conversion and Management, vol. 207, p. 112494, Mar. 2020, doi: 10.1016/j.enconman.2020.112494.
  13. [13] S. Yousefian, G. Bourque, and R. F. D. Monaghan, “Bayesian inference and uncertainty quantification for hydrogen-enriched and lean-premixed combustion systems,” International Journal of Hydrogen Energy, vol. 46, no. 46, pp. 23927–23942, Jul. 2021, doi: 10.1016/j.ijhydene.2021.04.153.
  14. [14] S. Krebs and C. Biet, “Predictive model of a premixed, lean hydrogen combustion for internal combustion engines,” Transportation Engineering, vol. 5, p. 100086, Sep. 2021, doi: 10.1016/j.treng.2021.100086.
  15. [15] A. A. Agama et al., “Effect of Graphene Oxide Addition on Spark Ignition Engine Performance and Cycle-to-cycle Variation with Gasoline-ethanol Fuel,” Automotive Experiences, vol. 9, no. 1, 2026, doi: 10.31603/ae.14237.
  16. [16] B. Enderle, B. Rauch, F. Grimm, G. Eckel, and M. Aigner, “Probabilistic Modeling and Uncertainty Quantification of Detailed Combustion Simulation for a Swirl Stabilized Spray Burner,” Flow, Turbulence and Combustion, vol. 111, no. 2, pp. 603–640, Aug. 2023, doi: 10.1007/s10494-023-00426-1.
  17. [17] W. Xu, T. Yang, C. Liu, K. Wu, and P. Zhang, “Transient identification of supersonic combustion mode by dynamic-VAE and Markov probabilistic modeling,” Combustion and Flame, vol. 284, p. 114609, Feb. 2026, doi: 10.1016/j.combustflame.2025.114609.
  18. [18] N. N. Smirnov and V. F. Nikitin, “Modeling and simulation of hydrogen combustion in engines,” International Journal of Hydrogen Energy, vol. 39, no. 2, pp. 1122–1136, Jan. 2014, doi: 10.1016/j.ijhydene.2013.10.097.
  19. [19] S. Verhelst, “Recent progress in the use of hydrogen as a fuel for internal combustion engines,” International Journal of Hydrogen Energy, vol. 39, no. 2, pp. 1071–1085, Jan. 2014, doi: 10.1016/j.ijhydene.2013.10.102.
  20. [20] R. Georgescu, C. Pana, N. Negurescu, A. Cernat, C. Nutu, and C. Sandu, “Aspects of the combustion variability analysis at an automotive engine fuelled with hydrogen,” IOP Conference Series: Materials Science and Engineering, vol. 1303, no. 1, p. 012017, Mar. 2024, doi: 10.1088/1757-899X/1303/1/012017.
  21. [21] K. Zhang and X. Jiang, “An assessment of fuel variability effect on biogas-hydrogen combustion using uncertainty quantification,” International Journal of Hydrogen Energy, vol. 43, no. 27, pp. 12499–12515, Jul. 2018, doi: 10.1016/j.ijhydene.2018.04.196.
  22. [22] R. Farzam and G. McTaggart-Cowan, “Hydrogen-diesel dual-fuel combustion sensitivity to fuel injection parameters in a multi-cylinder compression-ignition engine,” International Journal of Hydrogen Energy, vol. 49, pp. 850–867, Jan. 2024, doi: 10.1016/j.ijhydene.2023.09.124.
  23. [23] D. Cirrone, D. Makarov, C. Proust, and V. Molkov, “Minimum ignition energy of hydrogen-air mixtures at ambient and cryogenic temperatures,” International Journal of Hydrogen Energy, vol. 48, no. 43, pp. 16530–16544, May 2023, doi: 10.1016/j.ijhydene.2023.01.115.
  24. [24] A. Ghosh, N. M. Munoz-Munoz, and D. A. Lacoste, “Minimum ignition energy of hydrogen-air and methane-air mixtures at temperatures as low as 200 K,” International Journal of Hydrogen Energy, vol. 47, no. 71, pp. 30653–30659, Aug. 2022, doi: 10.1016/j.ijhydene.2022.07.017.
  25. [25] W. S. Nugroho, P. Purnami, A. M. S. Wahid, and I. N. G. Wardana, “Physics-informed neural network for temperature-dependent gas flow modeling in alkaline electrolyzers,” Applied Thermal Engineering, vol. 289, p. 129916, Mar. 2026, doi: 10.1016/j.applthermaleng.2026.129916.
  26. [26] J. Xiao et al., “Thermodynamic and heat transfer models for refueling hydrogen vehicles: Formulation, validation and application,” International Journal of Hydrogen Energy, vol. 52, pp. 172–190, Jan. 2024, doi: 10.1016/j.ijhydene.2023.06.081.
  27. [27] D. Levin and Y. Peres, Markov Chains and Mixing Times. Providence, Rhode Island: American Mathematical Society, 2017. doi: 10.1090/mbk/107.
  28. [28] P. Purnami, W. S. Nugroho, W. L. Anggayasti, Y. K. Sofi’i, and I. N. G. Wardana, “Markov decision process for current density optimization to improve hydrogen production by water electrolysis,” Electrochemistry Communications, vol. 177, p. 107987, Aug. 2025, doi: 10.1016/j.elecom.2025.107987.
  29. [29] A. I. Elwalid, D. Mitra, and T. E. Stern, “A Theory of Statistical Multiplexing of Markovian Sources: Spectral Expansions and Algorithms,” in Numerical Solution of Markov Chains, Boca Raton: CRC Press, 2021, pp. 223–238. doi: 10.1201/9781003210160-12.
  30. [30] V. Korohodskyi et al., “Development of a three-zone combustion model for stratified-charge spark-ignition engine,” Eastern-European Journal of Enterprise Technologies, vol. 2, no. 5 (110), pp. 46–57, Apr. 2021, doi: 10.15587/1729-4061.2021.228812.
  31. [31] J. M. Borg and A. C. Alkidas, “On the application of Wiebe functions to simulate normal and knocking spark-ignition combustion,” International Journal of Vehicle Design, vol. 49, no. 1/2/3, p. 52, 2009, doi: 10.1504/IJVD.2009.024240.
  32. [32] A. Aasen, V. G. Jervell, M. Hammer, B. A. Strøm, H. L. Skarsvåg, and Ø. Wilhelmsen, “Bulk and interfacial thermodynamics of ammonia, water and their mixtures,” Fluid Phase Equilibria, vol. 584, p. 114125, Sep. 2024, doi: 10.1016/j.fluid.2024.114125.
  33. [33] S. Sudarja, D. Deendarlianto, S. Sukamta, R. K. Adi, F. A. K. Yudha, and R. Arizona, “Experimental investigation of two-phase flow characteristics of nitrogen-CMC solution and nitrogen-XG solution in A 0.8 mm X 0.8 mm square capillary tube in a horizontal position,” Mechanical Engineering for Society and Industry, vol. 5, no. 2, pp. 542–559, Dec. 2025, doi: 10.31603/mesi.15041.
  34. [34] P. V. Manu, T. R. Navaneeth Kishan, and S. Jayaraj, “Thermodynamic Modelling and Experimental Investigation on a CI Engine Operated with Oxy-Hydrogen Gas as the Secondary Fuel,” in 26th National Conference on IC Engines and Combustion (NCICEC), 2021, pp. 303–314. doi: 10.1007/978-981-15-5996-9_23.
  35. [35] W. Wijayanti, M. N. Sasongko, and Purnami, “The calorific values of solid and liquid yields consequenced by temperatures of mahogany pyrolysis,” ARPN Journal of Engineering and Applied Sciences, vol. 11, no. 2, pp. 917–921, 2016.
  36. [36] R. C. Nugroho et al., “Prediction of Performance and Emission of Gasoline Engine Fueled with a Gasoline-Ethanol-Methanol Mixture Using One Dimensional Engine Modelling Based on Engine Test Results,” Automotive Experiences, vol. 7, no. 3, pp. 525–537, Dec. 2024, doi: 10.31603/ae.12141.
  37. [37] A. Yousefi, H. Guo, S. Dev, S. Lafrance, and B. Liko, “A study on split diesel injection on thermal efficiency and emissions of an ammonia/diesel dual-fuel engine,” Fuel, vol. 316, p. 123412, May 2022, doi: 10.1016/j.fuel.2022.123412.
  38. [38] E. D. Rokhmawati et al., “Numerical Study on the Effect of Mean Pressure and Loop’s Radius to the Onset Temperature and Efficiency of Traveling Wave Termoacustic Engine,” Automotive Experiences, vol. 3, no. 3, pp. 96–103, Sep. 2020, doi: 10.31603/ae.v3i3.3881.
  39. [39] D. Zhao et al., “Evaluation of the turbulent hot jet flame characteristics for achieving high thermal efficiency of hybrid engine,” Applied Thermal Engineering, vol. 236, p. 121611, Jan. 2024, doi: 10.1016/j.applthermaleng.2023.121611.
  40. [40] A. J. Mohammed and O. M. Ali, “Influence of hydrogen addition on the performance and emissions of gasoline engine,” Results in Engineering, vol. 26, p. 105426, Jun. 2025, doi: 10.1016/j.rineng.2025.105426.
  41. [41] L. Cardelli, R. Grosu, K. G. Larsen, M. Tribastone, M. Tschaikowski, and A. Vandin, “Algorithmic Minimization of Uncertain Continuous-Time Markov Chains,” IEEE Transactions on Automatic Control, vol. 68, no. 11, pp. 6557–6572, Nov. 2023, doi: 10.1109/TAC.2023.3244093.
  42. [42] A. Piano, G. Quattrone, F. Millo, F. Pesce, and A. Vassallo, “Development and validation of a predictive combustion model for hydrogen-fuelled internal combustion engines,” International Journal of Hydrogen Energy, vol. 89, pp. 1310–1320, Nov. 2024, doi: 10.1016/j.ijhydene.2024.09.407.
  43. [43] J. Chang, H. K. Chan, J. Lin, and W. Chan, “Non‐homogeneous continuous‐time Markov chain with covariates: Applications to ambulatory hypertension monitoring,” Statistics in Medicine, vol. 42, no. 12, pp. 1965–1980, May 2023, doi: 10.1002/sim.9707.
  44. [44] P. Purnami, W. S. N, I. P. Tama, W. W, Y. K. Sofi’i, and I. Wardana, “The analytic hierarchy process for the selection of water electrolysis electromagnetic ionization booster,” Electrochimica Acta, vol. 512, p. 145499, Feb. 2025, doi: 10.1016/j.electacta.2024.145499.
  45. [45] J. A. Caton, “Combustion phasing for maximum efficiency for conventional and high efficiency engines,” Energy Conversion and Management, vol. 77, pp. 564–576, Jan. 2014, doi: 10.1016/j.enconman.2013.09.060.
  46. [46] M. Ichiyanagi et al., “Combustion Analysis of Ammonia/Gasoline Mixtures at Various Injection Timing Conditions in a High Compression Ratio SI Engine with Sub-Chamber,” Automotive Experiences, vol. 7, no. 2, pp. 321–332, Sep. 2024, doi: 10.31603/ae.10533.
  47. [47] C. Hardiyanto and P. Prawoto, “Effect of Diethyl Ether on Performance and Exhaust Gas Emissions of Heavy-Duty Diesel Engines Fueled with Biodiesel-Diesel Blend (B35),” Automotive Experiences, vol. 6, no. 3, pp. 687–701, Dec. 2023, doi: 10.31603/ae.10311.
  48. [48] R. Soenoko, Purnami, and F. G. Utami Dewi, “Second stage cross flow turbine performance,” ARPN Journal of Engineering and Applied Sciences, vol. 12, no. 6, 2017.
  49. [49] E. Sangkilang, Sasmoko, W. Wijayanti, and I. Wardana, “The effect of sweet orange peel oil additive on virgin coconut oil combustion characteristic,” International Journal of Mechanical Engineering Technologies and Applications, vol. 7, no. 1, pp. 51–58, 2026, doi: 10.21776/mechta.2026.007.01.6.
  50. [50] O. Fujiwara and K. Kawamata, “Estimation of Spark Voltage and Spark Length Due to ESD Just before Collision between Charged Metal Spheres Using Measurement Waveforms of Radiated Electric Fields,” IEEJ Transactions on Fundamentals and Materials, vol. 145, no. 3, pp. 66–75, Mar. 2025, doi: 10.1541/ieejfms.145.66.
  51. [51] S. Saifullo, M. A. Batutah, A. Rizaly, P. Ponidi, H. Kusnanto, and I. Sofana, “Analysis of braking system on energy saving cars ‘Sakera’ mechanical engineering work, UM Surabaya,” International Journal of Mechanical Engineering Technologies and Applications, vol. 5, no. 1, pp. 1–11, Jan. 2024, doi: 10.21776/MECHTA.2024.005.01.1.
  52. [52] A. Nugroho, M. J. Winanto, I. Syafa’at, and R. D. Ratnani, “Performance diesel dual fuel engine on additional coconut shell oil,” International Journal of Mechanical Engineering Technologies and Applications, vol. 4, no. 2, pp. 144–153, Jun. 2023, doi: 10.21776/mechta.2023.004.02.4.
  53. [53] H. Delbari, S. Munshi, and G. McTaggart-Cowan, “Characterizing injection and ignition of hydrogen and hydrogen-methane blend fuels in a static combustion chamber,” Fuel, vol. 381, p. 133562, Feb. 2025, doi: 10.1016/j.fuel.2024.133562.
  54. [54] A. Firdiansyah, N. Ilminnafik, A. Triono, and M. N. Kustanto, “Effect of Biodiesel B100 and Ethanol Blends on the Performance of Small Diesel Engine,” International Journal of Mechanical Engineering Technologies and Applications, vol. 2, no. 2, p. 101, Jul. 2021, doi: 10.21776/mechta.2021.002.02.3.
  55. [55] H. Meng, C. Ji, G. Xin, J. Yang, K. Chang, and S. Wang, “Comparison of combustion, emission and abnormal combustion of hydrogen-fueled Wankel rotary engine and reciprocating piston engine,” Fuel, vol. 318, p. 123675, Jun. 2022, doi: 10.1016/j.fuel.2022.123675.
  56. [56] S. Guo, H. Meng, Q. Zhan, C. Ji, and D. Wang, “In-depth analysis of the key combustion parameters in the hydrogen-fueled Wankel rotary engine,” International Journal of Hydrogen Energy, vol. 100, pp. 58–66, Jan. 2025, doi: 10.1016/j.ijhydene.2024.12.325.
  57. [57] Y. Qiang et al., “Optimization of power performance and combustion stability of ultra-lean combustion in hydrogen fuel engines through combined turbulent jet ignition and variable valve timing,” Fuel, vol. 381, p. 133493, Feb. 2025, doi: 10.1016/j.fuel.2024.133493.
  58. [58] C. Park, Y. Kim, S. Oh, J. Oh, and Y. Choi, “Effect of the operation strategy and spark plug conditions on the torque output of a hydrogen port fuel injection engine,” International Journal of Hydrogen Energy, vol. 46, no. 74, pp. 37063–37070, Oct. 2021, doi: 10.1016/j.ijhydene.2021.08.229.
  59. [59] W. S. Nugroho, P. Purnami, F. A. Alamsyah, A. M. S. Wahid, and I. N. G. Wardana, “Analytical model for magnetic field assisted proton exchange membrane water electrolysis,” Journal of Power Sources, vol. 661, p. 238694, Jan. 2026, doi: 10.1016/j.jpowsour.2025.238694.
  60. [60] R. Novella, J. Gomez-Soriano, D. González-Domínguez, and O. Olaciregui, “Optimizing hydrogen spark-ignition engine performance and pollutants by combining VVT and EGR strategies through numerical simulation,” Applied Energy, vol. 376, p. 124307, Dec. 2024, doi: 10.1016/j.apenergy.2024.124307.
  61. [61] J. Zareei, A. Rohani, and W. M. F. Wan Mahmood, “Simulation of a hydrogen/natural gas engine and modelling of engine operating parameters,” International Journal of Hydrogen Energy, vol. 43, no. 25, pp. 11639–11651, Jun. 2018, doi: 10.1016/j.ijhydene.2018.02.047.
  62. [62] Y. Wang, X. Zhang, C. Li, and J. Wu, “Experimental and modeling study of performance and emissions of SI engine fueled by natural gas–hydrogen mixtures,” International Journal of Hydrogen Energy, vol. 35, no. 7, pp. 2680–2683, Apr. 2010, doi: 10.1016/j.ijhydene.2009.04.048.
  63. [63] B. Sun, D. Zhang, and F. Liu, “Investigation of the characteristics of hydrogen injector using experiment and simulation in hydrogen internal combustion engine,” International Journal of Hydrogen Energy, vol. 37, no. 17, pp. 13118–13124, Sep. 2012, doi: 10.1016/j.ijhydene.2012.03.169.
  64. [64] J. Zareei and A. Rohani, “Optimization and study of performance parameters in an engine fueled with hydrogen,” International Journal of Hydrogen Energy, vol. 45, no. 1, pp. 322–336, Jan. 2020, doi: 10.1016/j.ijhydene.2019.10.250.
  65. [65] T. Wang and P. Plecháč, “Steady-State Sensitivity Analysis of Continuous Time Markov Chains,” SIAM Journal on Numerical Analysis, vol. 57, no. 1, pp. 192–217, Jan. 2019, doi: 10.1137/18M119402X.
  66. [66] S. Meyn, R. L. Tweedie, and P. W. Glynn, Markov Chains and Stochastic Stability. Cambridge University Press, 2009. doi: 10.1017/CBO9780511626630.
  67. [67] O. R. N. Loasana, M. Iqbal, S. Soeparman, and L. Yuliati, “Performance modeling of PLTU Paiton 1 with variations in main steam pressure, temperature, and condenser pressure using gatecycle,” International Journal of Mechanical Engineering Technologies and Applications, vol. 7, no. 1, pp. 69–76, 2026, doi: 10.21776//mechta.2026.007.01.8.