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Abstract

In this study, we report biodiesel production from waste cooking oil using CaO catalyst derived from Madura limestone through a transesterification reaction. Many limestone quarries in Madura can be used as heterogeneous catalysts because they are cheap, easy to separate, and have high basicity. Conversion of limestone into CaO catalyst through calcination at 900°C for 3 hours. The CaO catalyst formed was characterized using X-Ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR), and Scanning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX) instruments. Biodiesel formed through the transesterification reaction was analyzed using GC-MS. Furthermore, biodiesel blends from waste cooking oil and pure diesel were prepared in volume percentages (B-10, B-20, B-30, B-40, and B-100) for testing on diesel engine performance. The results of testing the highest torque and brake horsepower (BHP) were obtained on pure diesel fuel (S-100) at 2.49 Nm and 381.12 watts, respectively. The lowest fuel consumption at 1500 rpm is produced on the B-20 at 0.186 kg/h. Overall, the emission characteristics of carbon monoxide (CO), nitrogen oxides (NOx), and nitrogen monoxide (NO) with the lowest concentration resulted from biodiesel blends rather than pure diesel.

Keywords

Biodiesel Waste cooking oil CaO Limestone Transesterification Diesel engine

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References

  1. F. Nadeem et al., “Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach,” Arabian Journal of Chemistry, vol. 14, no. 8, p. 103263, 2021, doi: 10.1016/j.arabjc.2021.103263.
  2. K. A. Abed, A. K. El Morsi, M. M. Sayed, A. A. E. Shaib, and M. S. Gad, “Effect of waste cooking-oil biodiesel on performance and exhaust emissions of a diesel engine,” Egyptian Journal of Petroleum, vol. 27, no. 4, pp. 985–989, 2018, doi: 10.1016/j.ejpe.2018.02.008.
  3. T. Kivevele, T. Raja, V. Pirouzfar, B. Waluyo, and M. Setiyo, “LPG-Fueled Vehicles: An Overview of Technology and Market Trend,” Automotive Experiences, vol. 3, no. 1, pp. 6–19, 2020, doi: 10.31603/ae.v3i1.3334.
  4. J. Kataria, S. K. Mohapatra, and K. Kundu, “Biodiesel production from waste cooking oil using heterogeneous catalysts and its operational characteristics on variable compression ratio CI engine,” Journal of the Energy Institute, vol. 92, no. 2, pp. 275–287, 2019, doi: 10.1016/j.joei.2018.01.008.
  5. M. Kuniyil et al., “Production of biodiesel from waste cooking oil using ZnCuO/N-doped graphene nanocomposite as an efficient heterogeneous catalyst,” Arabian Journal of Chemistry, vol. 14, no. 3, p. 102982, 2021, doi: 10.1016/j.arabjc.2020.102982.
  6. S. K. Bhatia et al., “Conversion of waste cooking oil into biodiesel using heterogenous catalyst derived from cork biochar,” Bioresource Technology, vol. 302, no. December 2019, p. 122872, 2020, doi: 10.1016/j.biortech.2020.122872.
  7. S. O. Gultom, “Mikroalga: Sumber Energi Terbarukan Masa Depan,” Jurnal Kelautan: Indonesian Journal of Marine Science and Technology, vol. 11, no. 1, p. 95, 2018, doi: 10.21107/jk.v11i1.3802.
  8. M. Setiyo, D. Yuvenda, and O. D. Samuel, “The Concise Latest Report on the Advantages and Disadvantages of Pure Biodiesel (B100) on Engine Performance: Literature Review and Bibliometric Analysis,” Indonesian Journal of Science and Technology, vol. 6, no. 3, pp. 469–490, 2021, doi: 10.17509/ijost.v6i3.38430.
  9. A. Sule, Z. A. Latiff, M. A. Abbas, I. Veza, and A. C. Opia, “Recent Advances in Diesel-Biodiesel Blended with Nano-Additive as Fuel in Diesel Engines: A Detailed Review,” Automotive Experiences, vol. 5, no. 2, pp. 182–216, 2022, doi: 10.31603/ae.6352.
  10. A. C. Arifin, A. Aminudin, and R. M. Putra, “Diesel-Biodiesel Blend on Engine Performance: An Experimental Study,” Automotive Experiences, vol. 2, no. 3, pp. 91–96, 2019, doi: 10.31603/ae.v2i3.2995.
  11. W. Roschat et al., “Catalytic performance enhancement of CaO by hydration-dehydration process for biodiesel production at room temperature,” Energy Conversion and Management, vol. 165, no. January, pp. 1–7, 2018, doi: 10.1016/j.enconman.2018.03.047.
  12. D. M. Marinković et al., “Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives,” Renewable and Sustainable Energy Reviews, vol. 56, pp. 1387–1408, 2016, doi: 10.1016/j.rser.2015.12.007.
  13. Y. Rathore, D. Ramchandani, and R. K. Pandey, “Experimental investigation of performance characteristics of compression-ignition engine with biodiesel blends of Jatropha oil & coconut oil at fixed compression ratio,” Heliyon, vol. 5, no. 11, p. e02717, 2019, doi: 10.1016/j.heliyon.2019.e02717.
  14. M. Vergel-Ortega, G. Valencia-Ochoa, and J. Duarte-Forero, “Experimental study of emissions in single-cylinder diesel engine operating with diesel-biodiesel blends of palm oil-sunflower oil and ethanol,” Case Studies in Thermal Engineering, vol. 26, no. December 2019, p. 101190, 2021, doi: 10.1016/j.csite.2021.101190.
  15. Z. Zhu et al., “Soybean biodiesel production using synergistic CaO/Ag nano catalyst: Process optimization, kinetic study, and economic evaluation,” Industrial Crops and Products, vol. 166, no. 666, p. 113479, 2021, doi: 10.1016/j.indcrop.2021.113479.
  16. A. Bhikuning, “The simulation of performance and emissions from rapeseed and soybean methyl ester in different injection pressures,” Automotive Experiences, vol. 4, no. 3, pp. 112–118, 2021, doi: 10.31603/ae.4682.
  17. M. Fadhlullah, S. N. B. Widiyanto, and E. Restiawaty, “The potential of nyamplung (Calophyllum inophyllum L.) seed oil as biodiesel feedstock: Effect of seed moisture content and particle size on oil yield,” Energy Procedia, vol. 68, no. 2015, pp. 177–185, 2015.
  18. Z. Rahmawati, H. Holilah, S. W. Purnami, H. Bahruji, T. P. Oetami, and D. Prasetyoko, “Statistical Optimisation using Taguchi Method for transesterification of Reutealis Trisperma Oil to Biodiesel on CaO-ZnO Catalysts,” Bulletin of Chemical Reaction Engineering & Catalysis, vol. 16, no. 3, pp. 686–695, 2021, doi: 10.9767/BCREC.16.3.10648.686-695.
  19. S. Supriyadi, P. Purwanto, D. D. Anggoro, and H. Hermawan, “The Effects of Sodium Hydroxide (NaOH) Concentration and Reaction Temperature on The Properties of Biodiesel from Philippine Tung (Reutealis Trisperma) Seeds,” Automotive Experiences, vol. 5, no. 1, pp. 57–67, 2022, doi: 10.31603/ae.5986.
  20. L. Díaz, D. Escalante, K. E. Rodríguez, Y. Kuzmina, and L. A. González, “Response surface methodology for continuous biodiesel production from Jatropha curcas oil using Li/pumice as catalyst in a packed-bed reactor assisted with diethyl ether as cosolvent,” Chemical Engineering and Processing - Process Intensification, vol. 179, no. May, 2022, doi: 10.1016/j.cep.2022.109065.
  21. M. J. Borah, A. Das, V. Das, N. Bhuyan, and D. Deka, “Transesterification of waste cooking oil for biodiesel production catalyzed by Zn substituted waste egg shell derived CaO nanocatalyst,” Fuel, vol. 242, no. May 2018, pp. 345–354, 2019, doi: 10.1016/j.fuel.2019.01.060.
  22. W. Xie and H. Wang, “Synthesis of heterogenized polyoxometalate-based ionic liquids with Brönsted-Lewis acid sites: A magnetically recyclable catalyst for biodiesel production from low-quality oils,” Journal of Industrial and Engineering Chemistry, vol. 87, pp. 162–172, 2020, doi: 10.1016/j.jiec.2020.03.033.
  23. X. F. Li, Y. Zuo, Y. Zhang, Y. Fu, and Q. X. Guo, “In situ preparation of K2CO3 supported Kraft lignin activated carbon as solid base catalyst for biodiesel production,” Fuel, vol. 113, pp. 435–442, 2013, doi: 10.1016/j.fuel.2013.06.008.
  24. T. F. Dossin, M. F. Reyniers, R. J. Berger, and G. B. Marin, “Simulation of heterogeneously MgO-catalyzed transesterification for fine-chemical and biodiesel industrial production,” Applied Catalysis B: Environmental, vol. 67, no. 1–2, pp. 136–148, 2006, doi: 10.1016/j.apcatb.2006.04.008.
  25. I. Istadi, U. Mabruro, B. A. Kalimantini, L. Buchori, and D. D. Anggoro, “Reusability and stability tests of calcium oxide based catalyst (K2O/CaO-ZnO) for transesterification of soybean oil to biodiesel,” Bulletin of Chemical Reaction Engineering & Catalysis, vol. 11, no. 1, pp. 34–39, 2016, doi: 10.9767/bcrec.11.1.413.34-39.
  26. A. Kolakoti, M. Setiyo, and M. L. Rochman, “A Green Heterogeneous Catalyst Production and Characterization for Biodiesel Production using RSM and ANN Approach,” International Journal of Renewable Energy Development, vol. 11, no. 3, pp. 703–712, 2022, doi: 10.14710/ijred.2022.43627.
  27. A. P. Purnamasari, M. E. F. Sari, D. T. Kusumaningtyas, S. Suprapto, A. Hamid, and D. Prasetyoko, “The effect of mesoporous H-ZSM-5 crystallinity as a CaO support on the transesterification of used cooking oil,” Bulletin of Chemical Reaction Engineering & Catalysis, vol. 12, no. 3, pp. 329–336, 2017, doi: 10.9767/bcrec.12.3.802.329-336.
  28. I. Dayi Febriana et al., “Pemanfaatan Batu Kapur Madura sebagai Katalis dalam Pembuatan Bioedesel dari Minyak Nyamplung,” IJCA (Indonesian Journal of Chemical Analysis), vol. 5, no. 1, pp. 09–17, 2022, doi: 10.20885/ijca.vol5.iss1.art2.
  29. A. Ketcong et al., “Production of fatty acid methyl esters over a limestone-derived heterogeneous catalyst in a fixed-bed reactor,” Journal of Industrial and Engineering Chemistry, vol. 20, no. 4, pp. 1665–1671, 2014, doi: 10.1016/j.jiec.2013.08.014.
  30. K. Ngaosuwan, W. Chaiyariyakul, O. Inthong, W. Kiatkittipong, D. Wongsawaeng, and S. Assabumrungrat, “La2O3/CaO catalyst derived from eggshells: Effects of preparation method and La content on textural properties and catalytic activity for transesterification,” Catalysis Communications, vol. 149, p. 106247, 2021, doi: 10.1016/j.catcom.2020.106247.
  31. A. Lesbani, S. O. Ceria Sitompul, R. Mohadi, and N. Hidayati, “Characterization and Utilization of Calcium Oxide (CaO) Thermally Decomposed from Fish Bones as a Catalyst in the Production of Biodiesel from Waste Cooking Oil,” Makara Journal of Technology, vol. 20, no. 3, p. 121, 2016, doi: 10.7454/mst.v20i3.3066.
  32. J. Cai, S. Wang, and C. Kuang, “A Modified Random Pore Model for Carbonation Reaction of CaO-based Limestone with CO2 in Different Calcination-carbonation Cycles,” Energy Procedia, vol. 105, pp. 1924–1931, 2017, doi: 10.1016/j.egypro.2017.03.561.
  33. N. Widiarti et al., “Upgrading catalytic activity of NiO/CaO/MgO from natural limestone as catalysts for transesterification of coconut oil to biodiesel,” Biomass Conversion and Biorefinery, 2021, doi: 10.1007/s13399-021-01373-5.
  34. D. Ayu, R. Aulyana, E. W. Astuti, K. Kusmiyati, and N. Hidayati, “Catalytic Transesterification of Used Cooking Oil to Biodiesel: Effect of Oil-Methanol Molar Ratio and Reaction Time,” Automotive Experiences, vol. 2, no. 3, pp. 73–77, 2019, doi: 10.31603/ae.v2i3.2991.
  35. A. Kolakoti, M. Setiyo, and B. Waluyo, “Biodiesel Production from Waste Cooking Oil: Characterization, Modeling and Optimization,” Mechanical Engineering for Society and Industry, vol. 1, no. 1, pp. 22–30, 2021, doi: 10.31603/mesi.5320.
  36. E. Permana and M. Naswir, “Kualitas Biodiesel Dari Minyak Jelantah Berdasarkan Proses Saponifikasi Dan Tanpa Saponifikasi,” JTT (Jurnal Teknologi Terapan), vol. 6, no. 1, p. 26, 2020, doi: 10.31884/jtt.v6i1.244.
  37. C. Sronsri, W. Sittipol, and K. U-yen, “Performance of CaO catalyst prepared from magnetic-derived CaCO3 for biodiesel production,” Fuel, vol. 304, no. July, p. 121419, 2021, doi: 10.1016/j.fuel.2021.121419.
  38. T. Maneerung, S. Kawi, Y. Dai, and C. H. Wang, “Sustainable biodiesel production via transesterification of waste cooking oil by using CaO catalysts prepared from chicken manure,” Energy Conversion and Management, vol. 123, pp. 487–497, 2016, doi: 10.1016/j.enconman.2016.06.071.
  39. A. R. Gupta and V. K. Rathod, “Waste cooking oil and waste chicken eggshells derived solid base catalyst for the biodiesel production: Optimization and kinetics,” Waste Management, vol. 79, pp. 169–178, 2018, doi: 10.1016/j.wasman.2018.07.022.
  40. O. N. Syazwani, S. H. Teo, A. Islam, and Y. H. Taufiq-Yap, Transesterification activity and characterization of natural CaO derived from waste venus clam (Tapes belcheri S.) material for enhancement of biodiesel production, vol. 105. 2017.
  41. J. Boro, L. J. Konwar, and D. Deka, “Transesterification of non edible feedstock with lithium incorporated egg shell derived CaO for biodiesel production,” Fuel Processing Technology, vol. 122, pp. 72–78, 2014, doi: 10.1016/j.fuproc.2014.01.022.
  42. F. J. S. Barros et al., “Glycerol oligomers production by etherification using calcined eggshell as catalyst,” Molecular Catalysis, vol. 433, pp. 282–290, 2017, doi: 10.1016/j.mcat.2017.02.030.
  43. M. Kouzu, T. Kasuno, M. Tajika, Y. Sugimoto, S. Yamanaka, and J. Hidaka, “Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production,” Fuel, vol. 87, no. 12, pp. 2798–2806, 2008, doi: 10.1016/j.fuel.2007.10.019.
  44. Rakhmad, N. Hindryawati, and Daniel, “Pembuatan Katalis Basa Heterogen Dari Batu Gamping ( Limestone ),” Prosiding Seminar Nasional, pp. 101–105, 2017.
  45. N. U. Soriano, R. Venditti, and D. S. Argyropoulos, “Biodiesel synthesis via homogeneous Lewis acid-catalyzed transesterification,” Fuel, vol. 88, no. 3, pp. 560–565, 2009, doi: 10.1016/j.fuel.2008.10.013.
  46. A. Kolakoti, P. R. Mosa, T. G. Kotaru, and M. Mahapatro, “Optimization of biodiesel production from waste cooking sunflower oil by taguchi and ann techniques,” Journal of Thermal Engineering, vol. 6, no. 5, pp. 712–723, 2020, doi: 10.18186/THERMAL.796761.
  47. A. Kolakoti and B. V. A. Rao, “Effect of fatty acid composition on the performance and emission characteristics of an IDI supercharged engine using neat palm biodiesel and coconut biodiesel as an additive,” Biofuels, vol. 10, no. 5, pp. 591–605, 2019, doi: 10.1080/17597269.2017.1332293.
  48. C. Sayin and M. Gumus, “Impact of compression ratio and injection parameters on the performance and emissions of a di diesel engine fueled with biodiesel-blended diesel fuel,” Applied Thermal Engineering, vol. 31, no. 16, pp. 3182–3188, 2011, doi: 10.1016/j.applthermaleng.2011.05.044.
  49. W. Saputro, J. Sentanuhady, A. I. Majid, W. Prasidha, N. P. Gunawan, and T. Y. Raditya, “Karakteristik Unjuk Kerja Mesin Diesel Menggunakan Bahan Bakar B100 dan B20 Dalam Jangka Panjang,” Journal of Mechanical Design and Testing, vol. 2, no. 2, p. 125, 2020, doi: 10.22146/jmdt.55523.
  50. A. Kolakoti, A. V. Kumar, R. Metta, M. Setiyo, and M. L. Rochman, “Experimental studies on in-cylinder combustion, exergy performance, and exhaust emission in a Compression Ignition engine fuelled with neat biodiesels,” Indonesian Journal of Science and Technology, vol. 7, no. 2, pp. 219–236, 2022.
  51. A. Hamid et al., “An Improvement of Catalytic Converter Activity Using Copper Coated Activated Carbon Derived from Banana Peel,” International Journal of Renewable Energy Development, vol. 12, no. 1, pp. 144–154, 2023, doi: 10.14710/ijred.2023.48739.
  52. S. Rasul, A. M. Kajal, and A. Khan, “Quantifying Uncertainty in Analytical Measurements,” Journal of Bangladesh Academy of Sciences, vol. 41, no. 2, pp. 145–163, 2018, doi: 10.3329/jbas.v41i2.35494.