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Abstract

Indonesia has an abundance of biomass from agricultural, plantation, and domestic waste products. Biomass can be converted into fuels and chemicals that are environmentally friendly. Empty fruit bunches (EFB) are biomass from abundant palm oil processing. Pyrolysis was a thermal process with free oxygen at temperatures between 400-600°C. Generally, pyrolysis was carried out under fast pyrolysis to produce a product that leads to bio-crude oil. One of the main components of bio-crude oil was phenol, which had been produced from further processing of crude oil. With the limitations of crude oil, the production of phenol from biomass pyrolysis was an option for the future, especially for fuels and fuel additives. Thus, it is necessary to investigate the effect of heating rate, temperature pyrolysis, and holding time on pyrolysis products including phenols in bio-crude oil. Slow pyrolysis of EFB was performed at various parameters, including temperatures (400, 450, and 500°C) and holding time (5, 10, and 15 min). Slow pyrolysis of oil palm EFB with variations in temperature and holding time has been carried out by producing liquid between (40 - 42 %weight), gas (19 – 21 % weight), and solid products (38 – 39  % weight). Biocrude oil liquid product showed the highest yield compared to biochar and bio pyrolysis gas. Temperature plays an important role in controlling the production of bio-crude oil as a liquid product, including a component in bio-crude oil. Phenol recovery was more affected by temperature instead of holding time.

Keywords

Biomass Empty Fruit Bunch (EFB) Slow Pyrolysis Bio Crude Oil Phenol

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References

  1. P. Elisa et al., “Environmental and climate change impacts of eighteen biomass-based plants in the alpine region: A comparative analysis,” Journal of Cleaner Production, 2020, doi: 10.1016/j.jclepro.2019.118449.
  2. S. Pang, “Advances in thermochemical conversion of woody biomass to energy, fuels and chemicals,” Biotechnology Advances. 2019, doi: 10.1016/j.biotechadv.2018.11.004.
  3. F. B. Ahmad, Z. Zhang, W. O. S. Doherty, and I. M. O’Hara, “The outlook of the production of advanced fuels and chemicals from integrated oil palm biomass biorefinery,” Renewable and Sustainable Energy Reviews. 2019, doi: 10.1016/j.rser.2019.04.009.
  4. J. P. Susanto, A. D. Santoso, and N. Suwedi, “Perhitungan Potensi Limbah Padat Kelapa Sawit untuk Sumber Energi Terbaharukan dengan Metode LCA,” Jurnal Teknologi Lingkungan, 2017, doi: 10.29122/jtl.v18i2.2046.
  5. Directorate General of Estates, “Statistik Perkebunan Indonesia Komoditas Kelapa Sawit Tahun 2018 - 2020,” pp. 1–82, 2019.
  6. A. Demirbaş, “Biomass resource facilities and biomass conversion processing for fuels and chemicals,” Energy Conversion and Management, 2001, doi: 10.1016/S0196-8904(00)00137-0.
  7. S. Y. Lee et al., “Waste to bioenergy: a review on the recent conversion technologies,” BMC Energy, 2019, doi: 10.1186/s42500-019-0004-7.
  8. A. Akhtar, V. Krepl, and T. Ivanova, “A Combined Overview of Combustion, Pyrolysis, and Gasification of Biomass,” Energy and Fuels. 2018, doi: 10.1021/acs.energyfuels.8b01678.
  9. M. Verma, S. Godbout, S. K. Brar, O. Solomatnikova, S. P. Lemay, and J. P. Larouche, “Biofuels production from biomass by thermochemical conversion technologies,” International Journal of Chemical Engineering. 2012, doi: 10.1155/2012/542426.
  10. A. V. Bridgwater, “Renewable fuels and chemicals by thermal processing of biomass,” Chemical Engineering Journal, 2003, doi: 10.1016/S1385-8947(02)00142-0.
  11. A. Pandey, T. Bhaskar, M. Stöcker, and R. K. Sukumaran, Recent Advances in Thermochemical Conversion of Biomass. 2015.
  12. P. Basu, Biomass gasification, pyrolysis and torrefaction: Practical design and theory. 2018.
  13. S. Mujiarto, B. Sudarmanta, H. Fansuri, and A. R. Saleh, “Comparative Study of Municipal Solid Waste Fuel and Refuse Derived Fuel in the Gasification Process Using Multi Stage Downdraft Gasifier,” Automotive Experiences, vol. 4, no. 2, 2021, doi: 10.31603/ae.4625.
  14. D. Neves, H. Thunman, A. Matos, L. Tarelho, and A. Gómez-Barea, “Characterization and prediction of biomass pyrolysis products,” Progress in Energy and Combustion Science. 2011, doi: 10.1016/j.pecs.2011.01.001.
  15. X. Hu and M. Gholizadeh, “Biomass pyrolysis: A review of the process development and challenges from initial researches up to the commercialisation stage,” Journal of Energy Chemistry. 2019, doi: 10.1016/j.jechem.2019.01.024.
  16. A. Irawan, S. Latifah Upe, and I. P. Meity Dwi, “Effect of torrefaction process on the coconut shell energy content for solid fuel,” in AIP Conference Proceedings, 2017, vol. 1826, doi: 10.1063/1.4979226.
  17. A. Irawan, T. Riadz, and N. Nurmalisa, “Proses torefaksi tandan kosong kelapa sawit untuk kandungan hemiselulosa dan uji kemampuan menyerap air,” Reaktor, 2015, doi: 10.14710/reaktor.15.3.190-194.
  18. S. Wang, G. Dai, H. Yang, and Z. Luo, “Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review,” Progress in Energy and Combustion Science, vol. 62. 2017, doi: 10.1016/j.pecs.2017.05.004.
  19. C. Liu, J. Hu, H. Zhang, and R. Xiao, “Thermal conversion of lignin to phenols: Relevance between chemical structure and pyrolysis behaviors,” Fuel, 2016, doi: 10.1016/j.fuel.2016.05.104.
  20. L. T. Nguyen, D. P. Phan, A. Sarwar, M. H. Tran, O. K. Lee, and E. Y. Lee, “Valorization of industrial lignin to value-added chemicals by chemical depolymerization and biological conversion,” Industrial Crops and Products, vol. 161. 2021, doi: 10.1016/j.indcrop.2020.113219.
  21. C. Zhao, A. Chen, E. Jiang, and L. Qin, “Pyrolysis of industrial waste lignin: Analysis of product yields and character,” Energy Sources, Part A: Recovery, Utilization and Environmental Effects, vol. 39, no. 5, 2017, doi: 10.1080/15567036.2016.1217293.
  22. G. Greco, C. Di Stasi, F. Rego, B. González, and J. J. Manyà, “Effects of slow-pyrolysis conditions on the products yields and properties and on exergy efficiency: A comprehensive assessment for wheat straw,” Applied Energy, 2020, doi: 10.1016/j.apenergy.2020.115842.
  23. S. Nanda, P. Mohanty, J. A. Kozinski, and A. K. Dalai, “Physico-Chemical Properties of Bio-Oils from Pyrolysis of Lignocellulosic Biomass with High and Slow Heating Rate,” Energy and Environment Research, vol. 4, no. 3, 2014, doi: 10.5539/eer.v4n3p21
  24. D. Mohan, C. U. Pittman, and P. H. Steele, “Pyrolysis of wood/biomass for bio-oil: A critical review,” Energy and Fuels, vol. 20, no. 3. 2006, doi: 10.1021/ef0502397.
  25. F. Febriyanti, N. Fadila, A. S. Sanjaya, Y. Bindar, and A. Irawan, “Pemanfaatan limbah tandan kosong kelapa sawit menjadi bio-char, bio-oil dan gas dengan metode pirolisis,” Jurnal Chemurgy, 2019, doi: 10.30872/CMG.V3I2.3578.
  26. S. Al Arni, “Comparison of slow and fast pyrolysis for converting biomass into fuel,” Renewable Energy, vol. 124, 2018, doi: 10.1016/j.renene.2017.04.060.
  27. M. P. Pandey and C. S. Kim, “Lignin Depolymerization and Conversion: A Review of Thermochemical Methods,” Chemical Engineering and Technology, vol. 34, no. 1. 2011, doi: 10.1002/ceat.201000270.
  28. A. R. Mohamed, Z. Hamzah, M. Z. M. Daud, and Z. Zakaria, “The effects of holding time and the sweeping nitrogen gas flowrates on the pyrolysis of EFB using a fixed bed reactor,” in Procedia Engineering, 2013, vol. 53, doi: 10.1016/j.proeng.2013.02.024.
  29. W. Peng, Q. Wu, and P. Tu, “Effects of temperature and holding time on production of renewable fuels from pyrolysis of Chlorella protothecoides,” Journal of Applied Phycology, vol. 12, no. 2, 2000, doi: 10.1023/A:1008115025002.
  30. Y. Le Brech et al., “The mechanism of biomass pyrolysis revealed by various analytical methods,” Hal, vol. 26, no. 10, 2014.
  31. T. J. Hilbers et al., “Cellulose-Lignin interactions during slow and fast pyrolysis,” Journal of Analytical and Applied Pyrolysis, vol. 114, 2015, doi: 10.1016/j.jaap.2015.05.020.
  32. T. Hosoya, H. Kawamoto, and S. Saka, “Cellulose-hemicellulose and cellulose-lignin interactions in wood pyrolysis at gasification temperature,” Journal of Analytical and Applied Pyrolysis, vol. 80, no. 1, 2007, doi: 10.1016/j.jaap.2007.01.006.
  33. T. Kan, V. Strezov, and T. J. Evans, “Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters,” Renewable and Sustainable Energy Reviews. 2016, doi: 10.1016/j.rser.2015.12.185.
  34. H. Paysepar, K. T. Venkateswara Rao, Z. Yuan, H. Shui, and C. Xu, “Production of phenolic chemicals from hydrolysis lignin via catalytic fast pyrolysis,” Journal of Analytical and Applied Pyrolysis, vol. 149, no. May, p. 104842, 2020, doi: 10.1016/j.jaap.2020.104842.
  35. Z. Liu, L. Wang, Y. Li, and Z. Li, “Study On Phenolic Content In Fast Pyrolysis Oil Obtained From The Model Compounds Of Three Major Components In Biomass,” 2016, doi: 10.2991/aeecs-16.2016.46.
  36. C. Setter, F. A. Borges, C. R. Cardoso, R. F. Mendes, and T. J. P. Oliveira, “Energy quality of pellets produced from coffee residue: Characterization of the products obtained via slow pyrolysis,” Industrial Crops and Products, vol. 154, 2020, doi: 10.1016/j.indcrop.2020.112731.
  37. M. S. Safdari, E. Amini, D. R. Weise, and T. H. Fletcher, “Heating rate and temperature effects on pyrolysis products from live wildland fuels,” Fuel, vol. 242, 2019, doi: 10.1016/j.fuel.2019.01.040.

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